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煤基碳点的制备和应用研究进展

Research Progress in Preparation and Application of Coal-based Carbon Dots

  • 摘要: 煤和煤衍生物的碳含量高、资源丰富,开发煤基碳材料及其制备技术具有重要的研究价值。碳点作为碳纳米材料家族冉冉升起的新星,由于其优异的光电性能、无毒性和良好的生物相容性等,在许多领域显示出巨大的应用前景。煤和煤衍生物是一种三维交联的网络状多晶材料,含有丰富的官能团和悬垂键,且芳香结构单元之间通过亚甲基、醚键等交联桥键连接,桥键可通过化学、电化学或物理方法来破坏。基于煤和煤衍生物的结构特点,综述煤基碳点的合成方法及其在电化学、光催化、化学分析、生物医药、光电材料等领域的应用,展望煤基碳点的未来发展方向。未来值得研究的方向为:优化合成工艺,实现高性能煤基碳点的规模化、绿色化制备;开发模拟、理论计算和其他先进技术,进一步探索煤基碳点及其复合材料结构和性能的调节机制;通过煤基碳点的改性和组装,拓展其应用领域。

     

    Abstract: Coal and coal derivatives have high carbon content and abundant resources, so it is of great research value to develop coal-based carbon materials and their preparation technology. As a rising star in the family of carbon nanomaterials, carbon dots (CDs) show great applications in many fields due to their excellent photoelectric properties, non-toxicity and good biocompatibility. Coal and coal derivatives are three-dimensional cross-linked network polycrystalline materials, containing rich functional groups and dangling bonds, and the aromatic structural units are connected by methylene, ether and other cross-linking bridge bonds. The bridge bonds can be destroyed by chemical, electrochemical or physical methods. Based on the structural characteristics of coal and coal derivatives, the synthesis methods of coal-based CDs and their applications in electrochemistry, photocatalysis, chemical analysis, biomedicine and photoelectric materials were reviewed, and the future development direction of coal-based CDs was prospected. The future research directions are as follows: optimizing the synthesis process to achieve the large-scale and green preparation of high-performance coal-based CDs; developing simulation, theoretical calculation and other advanced techniques to further explore the mechanism for regulating the structure and properties of coal-based CDs and their composites; expanding the application fields through the modification and assembly of coal-based CDs.

     

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