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海相淤泥轻质固化土的原位化学发泡法制备与性能表征

Preparation and Properties Characterization of Lightweight Solidified Soil of Marine Silt by In-situ Chemical Foaming Method

  • 摘要: 以矿物基胶凝材料为固化剂、铝粉膏为发泡剂,采用原位发泡法制备海相淤泥轻质固化土,研究固化剂掺量(1∶10~1∶4)、发泡剂掺量(0.025%~0.100%)及水灰比(0.6~1.2)对试样无侧限抗压强度、容重、吸水率、软化系数等指标性能的影响规律,并结合X射线衍射(XRD)和扫描电子显微镜(SEM)技术分析材料的微观结构演变与固化机理。结果表明:提高固化剂掺量可促进铝粉的发气反应,形成更发达的孔隙结构,在容重降至0.75 t/m3的同时实现无侧限抗压强度提升至1.06 MPa;而增加发泡剂掺量和提高水灰比则会导致材料容重和无侧限抗压强度的同步下降。在最优配比条件下(固化剂掺量为1∶4、发泡剂掺量为0.100%、水灰比为1.0) 28 d试样表现出优异的综合性能,无侧限抗压强度为1.06 MPa、容重为0.75 t/m3、软化系数为0.84。原因在于固化剂水化反应生成的水化硅酸钙(C—S—H)和钙矾石(AFt)等交织成网状结构,既可有效黏结颗粒又可合理调控孔隙分布,从而实现了轻质化与力学性能的协同优化。本文研究为填海造陆工程中软土地基加固材料的研发提供了重要参考依据。

     

    Abstract: Using mineral-based cementitious material as a curing agent and aluminum powder paste as a foaming agent, light-weight solidified soil dredged marine silt were prepared by in-situ foaming method. The influence law of curing agent content (1∶10−1∶4), foaming agent content (0.025%−0.100%), and water-to-binder ratio (0.6−1.2) on the unconfined compressive strength (UCS), bulk density, water absorption, softening coefficient of the samples were systematically investigated. The microstructural evolution and solidification mechanism were analyzed with X ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. The results show that increasing the curing agent content promotes the gas-generating reaction of aluminum powder, forming a more developed pore structure. This achieves a reduction in the bulk density to 0.75 t/m3 while improving the UCS to 1.06 MPa. However, higher foaming agent content and water-to-binder ratio led to a simultaneous decrease in both bulk density and UCS. Under the optimal mix proportion (curing agent content of 1∶4, foaming agent content of 0.100%, and water-to-binder ratio of 1.0), the 28 d sample exhibits excellent comprehensive performance, with a UCS of 1.06 MPa, bulk density of 0.75 t/m3, and softening coefficient of 0.84.The enhanced performance is attributed to the formation of a network structure composed of hydration products such as calcium silicate hydrate (C—S—H) and ettringite (AFt), which effectively bonds particles while regulating pore distribution, thereby achieving a synergistic optimization of lightweight characteristics and mechanical properties. This study provides important insights for the development of soft soil stabilization materials in land reclamation engineering.

     

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