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石墨烯增强模拟月壤地聚合物的动态压缩力学性能研究

Research on Dynamic Compressive Mechanical Properties of Graphene-enhanced Simulated Lunar Soil Geopolymer

  • 摘要: 采用Ф50 mm分离式霍普金森压杆(SHPB)试验系统,通过3.39~6.67 m/s的冲击速度范围和0~0.15%质量分数的石墨烯掺量,研究石墨烯增强模拟月壤地聚合物在动态压缩载荷下的力学响应特性。重点分析石墨烯掺量对材料动态抗压强度、能量耗散机制及破碎分形特征的影响规律,并借助扫描电子显微镜(SEM)揭示石墨烯在基体中的微观增强机理。结果表明:石墨烯增强模拟月壤地聚合物具有显著的应变率效应,其动态抗压强度和动态强度因子均随冲击速度线性增长;在固定冲击速度条件下,动态抗压强度随石墨烯掺量增加呈先升后略降趋势,最优掺量为0.10%(较未掺组强度提升14.75%),过量掺杂因石墨烯团聚效应导致强度下降。能量分析显示,入射能、吸收能与反射能均呈现先增长后稳定的变化规律,其中0.10%掺量组试样在6.67,4.49,3.39 m/s冲击速度下,入射能峰值分别达吸收能峰值的7.06,6.66,3.67倍。破碎体分形特征分析证实材料破碎后碎块分布具有高度自相似性。微观机理研究表明:石墨烯通过孔隙充填和微裂纹桥接作用有效抑制损伤扩展,促进能量耗散;同时作为成核位点加速地聚合反应,促进C—A—S—H和N—A—S—H胶凝相生成,形成多尺度增强结构。该研究为月球基地建筑材料在高应变率工况下的性能优化提供了重要试验支撑。

     

    Abstract: The dynamic compressive response characteristics of graphene-reinforced simulated lunar regolith geopolymer were investigated using a Φ50 mm split Hopkinson pressure bar (SHPB) test system with impact velocities ranging from 3.39 to 6.67 m/s and graphene contents varying from 0 to 0.15% (mass fraction). The effect of graphene content on the dynamic compressive strength, energy dissipation characteristics, and fragmentation fractal dimension was systematically analyzed. The microstructural reinforcement mechanisms of graphene in the matrix were characterized by scanning electron microscopy (SEM). The results demonstrate that the graphene-reinforced simulated lunar regolith geopolymer exhibits significant strain rate effects, with both dynamic compressive strength and dynamic strength factor showing linear increases with impact velocity. Under fixed impact velocities, the dynamic compressive strength first increases and then slightly decreases with increasing graphene content, reaching an optimal content of 0.10% (14.75% improvement compared to the control group), while excessive doping leads to strength reduction due to graphene agglomeration. Energy analysis reveals that the incident, absorbed and reflected energies all display initial growth followed by stabilization, with peak incident energies reaching 7.06, 6.66 and 3.67 times the peak absorbed energies at impact velocities of 6.67, 4.49 and 3.39 m/s respectively for the 0.1% graphene content group. Fractal analysis of fragmented specimens confirms highly self-similar distribution patterns of broken fragments. Microstructural investigations indicate that graphene effectively restricts damage propagation through pore-filling and microcrack-bridging mechanisms, thereby enhancing energy dissipation, while simultaneously serving as nucleation sites to accelerate geopolymerization reactions, promoting the formation of C—A—S—H and N—A—S—H gel phases and creating multiscale reinforcement structures. This study provides important experimental support for performance optimization of lunar base construction materials under high strain rate conditions.

     

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