高级检索

硫化物全固态锂金属电池负极界面优化策略研究进展

Research Progress on Optimization Strategies for Anode Interface Stability of Sulfide-based All-solid-state Lithium Metal Batteries

  • 摘要: 硫化物全固态锂金属电池采用金属锂负极和不可燃固态电解质,兼具高能量密度与高安全性能,被视为下一代储能和动力电池等领域的理想器件。然而,大多数硫化物固态电解质与锂金属之间界面不稳定,常导致锂枝晶生长、界面接触失效、循环稳定性差及库仑效率低等问题,严重制约其商业化应用。本文系统综述硫化物固态电解质与锂负极界面的关键挑战与研究进展,重点分析构建人工界面修饰层、开发合金负极、设计三维负极骨架结构以及电解质结构调控等4种主要改进策略。通过剖析现有界面改性策略的不足,进一步从深化多场耦合机制、构建复合界面层、创新界面结构设计以及人工智能驱动研究等维度对未来发展方向进行展望,旨在为开发高安全、长寿命的全固态锂金属电池提供理论依据与设计思路。

     

    Abstract: Sulfide-based all-solid-state lithium metal batteries enhance both energy density and safety by employing lithium metal anodes and non-flammable solid electrolytes, which are regarded as the ideal solution for next-generation energy storage and power battery applications. However, most sulfide-based solid electrolytes are unstable with lithium metal, prone to issues such as lithium dendrite growth, interface contact failure, poor cycling stability, and low coulombic efficiency during cycling. These problems severely hinder the commercial application of sulfide-based all-solid-state lithium metal batteries. This review provides a systematic overview of the key challenges at the interface between sulfide-based electrolytes and lithium metal anodes, offering a comprehensive summary of the latest research findings. Four primary improvement strategies are analyzed in depth: construction of artificial interface modification layer, development of lithium alloy anodes, design of three-dimensional anodes skeleton structure, and structural regulation of solid electrolytes. By thoroughly analyzing the shortcomings of existing interface modification strategies, and exploring future development directions through deepening multiphysics coupling mechanisms, constructing composite interface layers, innovating interface structure design, and AI-driven research, this review aims to provide theoretical foundations and design insights for developing highly safe, long-life all-solid-state lithium metal batteries.

     

/

返回文章
返回