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激光熔覆富铁高熵涂层研究进展

Research Progress of Laser Cladding Fe-rich High-entropy Coating

  • 摘要: 富铁高熵涂层由于原料成本显著低于镍基、钴基及钛基高熵合金体系,且可通过成分调控与钢铁、钛合金及铝合金等多种基体实现良好匹配,在表面防护领域展现出显著的工程应用潜力。本文系统综述了激光熔覆富铁高熵涂层的最新研究进展。首先,依据材料设计与相组成特征,将涂层划分为富铁高熵合金涂层、陶瓷增强富铁高熵复合涂层及富铁高熵非晶/纳米晶复合涂层三大体系,并阐述其组织演化规律。其次,探讨激光工艺参数对涂层微观组织与成形质量的影响机制,并梳理裂纹、气孔等典型缺陷的控制策略。进而,剖析涂层在复杂工况下的耐磨性、耐腐蚀性与抗高温氧化性能及其微观机理,并结合服役工况归纳其应用现状。最后,针对跨尺度缺陷控制、多场耦合下的性能设计及智能化制备等挑战,对未来的研究方向进行展望,以期为富铁高熵涂层的工程化应用提供理论参考。

     

    Abstract: Iron-rich high-entropy coatings are endowed with unique engineering application potential in the field of surface protection, owing to their significantly lower raw material cost than that of Ni-based, Co-based and Ti-based high-entropy systems, and their ability to match various substrates including steel, titanium alloys and aluminum alloys through compositional tuning. The recent research progress of laser-clad iron-rich high-entropy coatings was systematically reviewed. First, according to the material design and phase composition characteristics, the coatings were classified into three major systems, namely iron-rich high-entropy alloy coatings, ceramic-reinforced iron-rich high-entropy composite coatings, and iron-rich high-entropy amorphous/nanocrystalline composite coatings, and their microstructural evolution laws were elaborated. Second, the regulation mechanisms of laser process parameters on the coating microstructure and forming quality were investigated, and the control strategies for typical defects such as cracks and pores were systematically summarized. Furthermore, the wear resistance, corrosion resistance and high-temperature oxidation resistance of the coatings under complex service conditions, as well as their underlying micro-mechanisms, were thoroughly analyzed, and their application status in various fields was summarized according to service conditions. Finally, prospects were put forward regarding the challenges of cross-scale defect control, multi-field coupling performance design and intelligent fabrication, in order to provide theoretical reference for promoting the engineering application of iron-rich high-entropy coatings.

     

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