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石墨烯增强铝基复合材料的制备及其性能

Preparation of Graphene Reinforced Aluminum Matrix Composites and its Properties

  • 摘要: 采用球磨混粉及放电等离子烧结技术制备不同含量(石墨烯质量分数为0,0.2%,0.5%,0.8%,1.0%)的石墨烯铝基复合材料,利用扫描电子显微镜、能量色散谱仪、X射线衍射、拉曼光谱仪和X射线光电子能谱表征铝基复合材料的微观组成、缺陷及烧结样品表面元素的化学价态,研究石墨烯含量对铝基复合材料导热性能和显微硬度的影响。结果表明:添加石墨烯后铝基复合材料的显微硬度和导热系数均有提高,导热系数提高更为显著;当石墨烯质量分数为0.2%时,铝基复合材料的显微硬度和导热系数达到最大值,与铝基体材料相比其硬度提高24%,导热系数提高204%;但当石墨烯质量分数继续增加到0.5%,0.8%,1.0%时,铝基复合材料的显微硬度及导热系数并未明显提升,主要原因为随着石墨烯含量的增加,石墨烯片层间的团聚现象加重,从而导致铝基复合材料的显微硬度与导热系数无法再进一步有效提高。

     

    Abstract: Different contents of graphene aluminum matrix composites (mass fraction of 0, 0.2%, 0.5%, 0.8%, 1.0%) were prepared by ball milling and discharge plasma sintering technology. Scanning electron microscope, energy dispersion spectrometer, X ray diffraction, Raman spectrometer, and X ray photoelectron spectroscopy were used to characterize the microstructure, defectsand chemical valence of surface elements of the sintered samples. And the influence of graphene content on the thermal conductivity and microhardness of aluminum matrix composites were studied. The results show that adding graphene can improve the microhardness and thermal conductivity of aluminum matrix composites, and the increase of thermal conductivity is more significant. For the composites with 0.2% mass fraction of graphene, both the microhardness and thermal conductivityreach the maximum values, compared with aluminum matrix materials, the microhardness and thermal conductivity of composite materials was increased by 24% and 204%, respectively. However, when the mass fraction of graphene continues to increase to 0.5%, 0.8% and 1.0%, the microhardness and thermal conductivity of the composites do not increase significantly.The main reason is that with the increase of graphene content,the agglomeration between graphene sheets becomes more serious, which leads to the failure of further improvement of microhardness and thermal conductivity of aluminum matrix composites.

     

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