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生姜提取物对Q235钢在盐酸溶液中的缓蚀作用

Inhibition Effect of Ginger Extract on Q235 Steel in Hydrochloric Acid

  • 摘要: 通过乙醇回流提取法制备生姜提取物(GE),研究GE对Q235钢在浓度为1 mol/L HCl溶液中的缓蚀作用及作用机理。结果显示:GE对Q235钢的缓蚀性能随其浓度的增大而增强,40 ℃时GE质量浓度0.20 g/L后,缓蚀率趋于稳定,达93%以上;GE对钢片的吸附符合Langmuir吸附等温方程,是一种混合型缓蚀剂,主要抑制阴极反应;添加GE后钢/酸界面的电荷转移电阻增大,腐蚀反应速率减缓,对碳钢腐蚀具有较强的抑制作用。

     

    Abstract: Ginger extract (GE) was prepared by ethanol reflux extraction method. The inhibition effect and mechanism of GE on Q235 carbon steel in 1 mol/L HCl solution were studied. The results show that the corrosion inhibition performance of GE on Q235 steel increases with the increase of its concentration. After the mass concentration of GE reaches 0.20 g/L at 40 ℃, the corrosion inhibition rate tends to be stable, up to more than 93%. The adsorption of GE on the steel sheet conforms to Langmuir adsorption isotherm equation, and it is a mixed corrosion inhibitor, which mainly inhibits the cathode reaction. After adding GE, the charge transfer resistance of steel/acid interface increases, the corrosion reaction rate slows down, and has a strong inhibition effect on the corrosion of carbon steel.

     

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