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基于正交试验的铁尾矿烧结透水砖性能影响因素分析

Analysis of Influencing Factors on Properties of Permeable Brick Sintered with Iron Tailings Based on Orthogonal Test

  • 摘要: 以铁尾矿为主要原料、膨胀珍珠岩为造孔剂,掺入煤气化灰渣和钠长石制备铁尾矿烧结透水砖。采用正交试验研究灰渣比、膨胀珍珠岩掺量和粒径、烧结温度和保温时间对烧结透水砖力学和透水性能的影响,且对烧结产物的微观形貌进行分析。结果表明:透水砖的抗折和抗压强度随铁尾矿掺量的增加而提升,透水性能随膨胀珍珠岩掺量与粒径的增加而提升;透水砖烧结产物主要晶相为赤铁矿、石英、莫来石矿物及透辉石;m(煤铁尾矿)∶m(气化灰)∶m(钠长石)=85∶7.5∶7.5时,掺入质量分数20%、粒径0.45~0.90 mm的膨胀珍珠岩造孔剂,在1090℃下保温1 h可制得综合性能好的烧结透水砖,内部连通孔隙直径大、数量多,抗折强度为3.74 MPa、抗压强度为18.41 MPa、透水系数为0.011 cm/s、气孔率为28.57%,其性能满足GB/T 25993— 2010中的Rf3.5抗折强度等级要求。

     

    Abstract: Taking iron tailings as the main raw material, expanded perlite as pore forming agent, the coal gasification ash and albite were added to prepare iron tailings sintered permeable brick. The effects of ash/slag ratio, the content of expanded perlite, the particle size of expanded perlite, sintering temperature and heat preservation on the mechanical properties and permeability of sintered permeable brick were investigated through the orthogonal experiment, and the micro-morphologies of sintered products were analyzed. The results show that the flexural and compressive strengths of permeable brick increase with the increase of iron tailings content, the permeability increases with the increase of the content and particle size of expanded perlite. The main crystalline phases of sintering products of permeable brick are hematite, quartz, mullite minerals and diopside. When m(iron tailings)∶ m(coal gasification ash)∶m(albite)=85∶7.5∶7.5, mixed with expanded perlite pore forming agent with mass fraction of 20% and particle size of 0.45-0.90 mm, at the sintering temperature of 1 090 ℃ for 1 h, the sintered permeable brick with good comprehensive performance can be prepared, and the internal connecting pore diameter is large and many, with flexural strength of 3.74 MPa, compressive strength of 18.41 MPa, permeability coefficient of 0.011 cm/s and porosity of 28.57%, its performance can meet the Rf3.5 flexural strength grade requirements in GB/T 25993—2010.

     

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