Advance Search
HU Mengjie, CUI Yujie, QIAN Tingting, XIN Zhifeng, JIA Aiquan, ZHANG Qianfeng. Synthesis and Crystal Structures of New Sulfido/oxo-molybdenum Complexes (Et4N)2[MoO(S4)(bdtX2)]and (Et4N)2[Mo2O2(μ2-S)2(bdtX2)] (X=H and Cl)[J]. Journal of Anhui University of Technology（Natural Science）, 2018, 35(1): 32-38. DOI: 10.3969/j.issn.1671-7872.2018.01.007
Citation: HU Mengjie, CUI Yujie, QIAN Tingting, XIN Zhifeng, JIA Aiquan, ZHANG Qianfeng. Synthesis and Crystal Structures of New Sulfido/oxo-molybdenum Complexes (Et4N)2[MoO(S4)(bdtX2)]and (Et4N)2[Mo2O2(μ2-S)2(bdtX2)] (X=H and Cl)[J]. Journal of Anhui University of Technology（Natural Science）, 2018, 35(1): 32-38. DOI: 10.3969/j.issn.1671-7872.2018.01.007
shu

Synthesis and Crystal Structures of New Sulfido/oxo-molybdenum Complexes (Et4N)2MoO(S4)(bdtX2)and (Et4N)2Mo2O2(μ2-S)2(bdtX2) (X=H and Cl)

    Graphical Abstract
    • Abstract
  • Substitution of (Et4N)2MoIVO(S4)2 in acetonitrile with mole ratio(1:1) 1,2-benzenedithiol (H2bdt) and 3,6-dichloro-1,2-benzenedithiol (H2bdtCl2) gave mono(dithiolene)oxo-molybdenum(IV) complexes (Et4N)2MoO(S4)(bdtX2) (X=H, 1; X=Cl, 2). Treatment of 1 and 2 with additional equimolar amount of 1,2-arenedithiol in warm acetonitrile afforded bis(µ-sulfido)dimolybdenum(V) species (Et4N)2Mo2O2(μ2-S)2(bdtX2)2 (X=H, 3;X=Cl, 4). All four complexes were characterized spectroscopically with UV- 3000 spectrophotometer, of which complexes 2, 3 and 4 have been further determined with single-crystal X-ray diffraction. Results show the synisomers are formed referring to the position of the apical oxo ligands with respect to the Mo2S2 plane.
    • FullText(HTML)
  • loading
    • References (18)
    • Related Articles
  • Supplements (0)

Catalog

    Turn off MathJax
    Article Contents

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return